Foods and Raw Materials Foods and Raw Materials Foods and Raw Materials 2308-4057 2310-9599 27329 10.21603/2308-4057-2018-1-230-241 CHEMISTRY AND ECOLOGY CHEMISTRY AND ECOLOGY CHEMISTRY AND ECOLOGY EFFECT OF PRIORITY DRINKING WATER CONTAMINANTS ON THE QUALITY INDICATORS OF BEVERAGES DURING THEIR PRODUCTION AND STORAGE EFFECT OF PRIORITY DRINKING WATER CONTAMINANTS ON THE QUALITY INDICATORS OF BEVERAGES DURING THEIR PRODUCTION AND STORAGE Краснова Тамара Андреевна Krasnova Tamara Andreevna ecolog1528@yandex.ru

доктор технических наук;

doctor of technical sciences;

 https://orcid.org/0000-0002-1349-2812 Тимощук Ирина Вадимовна Timoshchuk Irina V. irina_190978@mail.ru https://orcid.org/0000-0002-3782-2521 Горелкина Алена Константиновна Gorelkina Alena K.

кандидат химических наук;

candidate of chemical sciences;

 Беляева Оксана Владимировна Belyaeva Oksana V. еcolog1528@yandex.ru Кемеровский государственный университет Кемерово Россия Kemerovo State University Kemerovo Russian Federation Кемеровский государственный университет Кемерово Россия Kemerovo State University Kemerovo Russian Federation Кемеровский государственный университет Кемерово Россия Kemerovo State University Kemerovo Russian Federation ФГБОУ ВО «Кемеровский государственный университет» Кемерово Россия Kemerovo State University Kemerovo Russian Federation 6 1 230 241 http://jfrm.ru/?page=archive&jrn=11&article=26

Currently, water from the centralized domestic drinking water supply system is mainly used to make non- alcoholic carbonated beverages and nectars. The classical technology does not always provide the purification of water from organic compounds. In addition, during water preparation, at the primary chlorination stage, chlorine-containing organic compounds (chloroform, dichloroethane, trichlorethylene, etc.) are formed due to the interaction of chlorine with natural organic substances. The by-products of natural water treatment by chloragents, in addition to the toxic and carcinogenic effects, can interact with the main components of products reducing their quality. Such water cannot be used for drinking purposes and in food production without the additional post-treatment. The results of the study of the effect of organic impurities present in water (chloroform, trichlorethylene and dichloroethane) on the stability of the components of non-alcoholic carbonated beverages (sodium benzoate, sucrose, citric acid, natural and synthetic dyes and vanillin) and nectars (color stability, vitamins A, C, group B) have been provided. The studies were carried out in the Kemerovo region using gas-liquid chromatography, molecular absorption spectroscopy, refractometry and capillary electrophoresis. The concentration of the main components of non-alcoholic carbonated beverages, nectars and priority contaminants (trichlorethylene and dichloroethane) has been reduced. It has been shown that chloroform does not come into chemical interaction with the components of beverages. The mechanism of interaction of sucrose, citric acid, sodium benzoate, vanillin, vitamins in non-alcoholic carbonated beverages and nectars with trichlorethylene and dichloroethane has been theoretically justified. It has been established that dichloroethane and trichlorethylene have a significant effect on the resistance of the main components of non-alcoholic carbonated beverages, with the exception of dyes, and also on the intensity of color and the preservation of vitamins of nectars, reducing the quality characteristics of beverages during production and storage.

Currently, water from the centralized domestic drinking water supply system is mainly used to make non- alcoholic carbonated beverages and nectars. The classical technology does not always provide the purification of water from organic compounds. In addition, during water preparation, at the primary chlorination stage, chlorine-containing organic compounds (chloroform, dichloroethane, trichlorethylene, etc.) are formed due to the interaction of chlorine with natural organic substances. The by-products of natural water treatment by chloragents, in addition to the toxic and carcinogenic effects, can interact with the main components of products reducing their quality. Such water cannot be used for drinking purposes and in food production without the additional post-treatment. The results of the study of the effect of organic impurities present in water (chloroform, trichlorethylene and dichloroethane) on the stability of the components of non-alcoholic carbonated beverages (sodium benzoate, sucrose, citric acid, natural and synthetic dyes and vanillin) and nectars (color stability, vitamins A, C, group B) have been provided. The studies were carried out in the Kemerovo region using gas-liquid chromatography, molecular absorption spectroscopy, refractometry and capillary electrophoresis. The concentration of the main components of non-alcoholic carbonated beverages, nectars and priority contaminants (trichlorethylene and dichloroethane) has been reduced. It has been shown that chloroform does not come into chemical interaction with the components of beverages. The mechanism of interaction of sucrose, citric acid, sodium benzoate, vanillin, vitamins in non-alcoholic carbonated beverages and nectars with trichlorethylene and dichloroethane has been theoretically justified. It has been established that dichloroethane and trichlorethylene have a significant effect on the resistance of the main components of non-alcoholic carbonated beverages, with the exception of dyes, and also on the intensity of color and the preservation of vitamins of nectars, reducing the quality characteristics of beverages during production and storage.

 Chloroform trichlorethylene dichloroethane drinking water carbonated non-alcoholic beverages nectars quality indicators Chloroform trichlorethylene dichloroethane drinking water carbonated non-alcoholic beverages nectars quality indicators

Krasnova Т.А. and Skolubovich Yu.L. Obezzarazhivanie vody v sisteme pit'evogo vodosnabzheniya: [Water disinfection in a drinking water supply system]. Novosibirsk: NSUACE Publ., 2012. 114 p. Krasnova T.A. and Skolubovich Yu.L. Obezzarazhivanie vody v sisteme pit'evogo vodosnabzheniya: [Water disinfection in a drinking water supply system]. Novosibirsk: NSUACE Publ., 2012. 114 p. Eldyshev Yu.N. Potable water - a trouble of the country. Ecology and life, 2008, no. 9, pp. 19-23. (In Russian). Eldyshev Yu.N. Potable water - a trouble of the country. Ecology and life, 2008, no. 9, pp. 19-23. (In Russian). Materialy k gosudarstvennomu dokladu «O sostoyanii i okhrane okruzhayushchey sredy Kemerovskoy oblasti v 2016 godu» [Materials for the state report "On the state and protection of the environment of the Kemerovo Region in 2016"]. Kemerovo: Department of Natural Resources and Ecology of the Kemerovo Region, 2016. Available at: http://kuzbasseco.ru/wp-content/uploads/2017/06/Доклад-2016.pdf. (accessed 18 January 2018). Materialy k gosudarstvennomu dokladu «O sostoyanii i okhrane okruzhayushchey sredy Kemerovskoy oblasti v 2016 godu» [Materials for the state report "On the state and protection of the environment of the Kemerovo Region in 2016"]. Kemerovo: Department of Natural Resources and Ecology of the Kemerovo Region, 2016. Available at: http://kuzbasseco.ru/wp-content/uploads/2017/06/Doklad-2016.pdf. (accessed 18 January 2018). Borisov B.A., Egorova E.Yu., and Zainullin R.A. Vodopodgotovka v proizvodstve pishchevykh produktov i napitkov [Water treatment in food and beverage production]. St. Petersburg: Professija Publ., 2014. 398 p. Borisov B.A., Egorova E.Yu., and Zainullin R.A. Vodopodgotovka v proizvodstve pishchevykh produktov i napitkov [Water treatment in food and beverage production]. St. Petersburg: Professija Publ., 2014. 398 p. Cooper C. and Burch R. An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water preparation. Water Research, 1999, vol. 33, no. 18, pp. 3695-3700. DOI: 10.1016/S0043-1354(99)00091-3. Cooper C. and Burch R. An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water preparation. Water Research, 1999, vol. 33, no. 18, pp. 3695-3700. DOI: 10.1016/S0043-1354(99)00091-3. Mitsuyuki M. and Kiyoshi K. Advanced Treatment of Waste Water Containing Dichloromethane and Chloroform with Reverse Osmosis Membrane. Science and Industry, 2002, vol. 76, no. 9, pp. 421-430. (In Japanese). Mitsuyuki M. and Kiyoshi K. Advanced Treatment of Waste Water Containing Dichloromethane and Chloroform with Reverse Osmosis Membrane. Science and Industry, 2002, vol. 76, no. 9, pp. 421-430. (In Japanese). Kirsanov M.P. and Shishkin V.V. Еvaluating and improving the efficiency of the use of activated carbons for the extraction of organochlorine compounds in water treatment technology. Foods and Raw Materials, 2016, vol. 4, no. 1, pp. 148-153. DOI: 10.21179/2308-4057-2016-1-148-153. Kirsanov M.P. and Shishkin V.V. Evaluating and improving the efficiency of the use of activated carbons for the extraction of organochlorine compounds in water treatment technology. Foods and Raw Materials, 2016, vol. 4, no. 1, pp. 148-153. DOI: 10.21179/2308-4057-2016-1-148-153. Baytak D., Sofuoglu A., Inal F, and Sofuoglu S.C. Seasonal variation in drinking water concentrations of disinfection by-products in IZMIR and associated human health risks. Science of the Total Environment, 2008, vol. 407, no. 1, рр. 286-296. DOI: 10.1016/j.scitotenv.2008.08.019. Baytak D., Sofuoglu A., Inal F, and Sofuoglu S.C. Seasonal variation in drinking water concentrations of disinfection by-products in IZMIR and associated human health risks. Science of the Total Environment, 2008, vol. 407, no. 1, rr. 286-296. DOI: 10.1016/j.scitotenv.2008.08.019. Krasnova T.A., Timosсhuk I.V., Gorelkina A.K., and Dugarjav J. The choice of sorbent for adsorption extraction of chloroform from drinking water. Foods and Raw materials, 2017, vol. 5, no. 2, pp.189-196. DOI: 10.21603/2308-4057-2017-2-189-196. Krasnova T.A., Timosshuk I.V., Gorelkina A.K., and Dugarjav J. The choice of sorbent for adsorption extraction of chloroform from drinking water. Foods and Raw materials, 2017, vol. 5, no. 2, pp.189-196. DOI: 10.21603/2308-4057-2017-2-189-196. Krasnova Т.А. Vliyanie prioritetnykh zagryazniteley pit'evoy vody na kachestvo bezalkogol'nykh napitkov i vosstanovlennykh molochnykh produktov [Effect of priority pollutants of drinking water on the quality of soft drinks and reconstituted dairy products]. Kemerovo: KemIFST Publ., 2013. 142 p. Krasnova T.A. Vliyanie prioritetnykh zagryazniteley pit'evoy vody na kachestvo bezalkogol'nykh napitkov i vosstanovlennykh molochnykh produktov [Effect of priority pollutants of drinking water on the quality of soft drinks and reconstituted dairy products]. Kemerovo: KemIFST Publ., 2013. 142 p. Boku D.S. and Siyanova N.A. Production control of swimming pool water for chloroform. Health. Medical ecology. Science, 2012, vols 49-50, nos 3-4, pp. 86-87. (In Russian). Boku D.S. and Siyanova N.A. Production control of swimming pool water for chloroform. Health. Medical ecology. Science, 2012, vols 49-50, nos 3-4, pp. 86-87. (In Russian). Bove G.E., Rogerson P.A., and Vena J.E. Case control study of the geographic variability of exposure to disinfectant byproducts and risk for rectal cancer. International Journal of Health Geographics, 2007, vol. 6, article number 18. DOI: 10.1186/1476-072X-6-18. Bove G.E., Rogerson P.A., and Vena J.E. Case control study of the geographic variability of exposure to disinfectant byproducts and risk for rectal cancer. International Journal of Health Geographics, 2007, vol. 6, article number 18. DOI: 10.1186/1476-072X-6-18. Hwang B.F., Jaakkola J.J.K., and Guo H.R. Water disinfection by-products and the risk of specific birth defects: A population-based cross-sectional study in Taiwan. Environmental Health: A Global Access Science Source, 2008, vol. 7, no. 1, article number 23. DOI: 10.1186/1476-069X-7-23. Hwang B.F., Jaakkola J.J.K., and Guo H.R. Water disinfection by-products and the risk of specific birth defects: A population-based cross-sectional study in Taiwan. Environmental Health: A Global Access Science Source, 2008, vol. 7, no. 1, article number 23. DOI: 10.1186/1476-069X-7-23. Nieuwenhuijsen M.J., Grellier J., Smith R., et al. The epidemiology and possible mechanisms of disinfection byproducts in drinking water. Philosophical Transaction of The Royal Society A: Physical, Mathematical and Engineering Sciences, 2009, vol. 367, no. 1904, рр. 4043-4076. DOI: 10.1098/rsta.2009.0116. Nieuwenhuijsen M.J., Grellier J., Smith R., et al. The epidemiology and possible mechanisms of disinfection byproducts in drinking water. Philosophical Transaction of The Royal Society A: Physical, Mathematical and Engineering Sciences, 2009, vol. 367, no. 1904, rr. 4043-4076. DOI: 10.1098/rsta.2009.0116. Ludewig R. and Los K. Ostrye otravleniya [Acute poisoning]. Moscow: Meditsina Publ., 1983. 560 p. Ludewig R. and Los K. Ostrye otravleniya [Acute poisoning]. Moscow: Meditsina Publ., 1983. 560 p. Timoshchuk I.V. Technology of after purification of drinking water from organic contaminants in the production of foodstuffs. Foods and Raw Materials, 2016, vol. 4, no. 1, рр. 61-69. DOI: 10.21179/2308-4057-2016-1-61-69. Timoshchuk I.V. Technology of after purification of drinking water from organic contaminants in the production of foodstuffs. Foods and Raw Materials, 2016, vol. 4, no. 1, rr. 61-69. DOI: 10.21179/2308-4057-2016-1-61-69. Dziomba S., Kowalski P., and Baczek T. Field-amplified sample stacking-sweeping of vitamins B determination in capillary electrophoresis. Journal оf Chromatography A, 2012, vol. 1267, pp. 224-230. DOI: 10.1016/j.chroma.2012.07.068. Dziomba S., Kowalski P., and Baczek T. Field-amplified sample stacking-sweeping of vitamins B determination in capillary electrophoresis. Journal of Chromatography A, 2012, vol. 1267, pp. 224-230. DOI: 10.1016/j.chroma.2012.07.068. Zhao D., Lu M., and Cai Z. Separation and determination of B vitamins and essential amino acids in health drinks by CE-LIF with simultaneous derivatization. Electrophoresis, 2012, vol. 33, no. 15, pp. 2424-2432. DOI: 10.1002/elps.201200040. Zhao D., Lu M., and Cai Z. Separation and determination of B vitamins and essential amino acids in health drinks by CE-LIF with simultaneous derivatization. Electrophoresis, 2012, vol. 33, no. 15, pp. 2424-2432. DOI: 10.1002/elps.201200040. Wolfson N.S. (ed.). Preparativnaya organicheskaya khimiya [Preparative Organic Chemistry]. Moscow: HCI Publ., 1959. 889 p. Wolfson N.S. (ed.). Preparativnaya organicheskaya khimiya [Preparative Organic Chemistry]. Moscow: HCI Publ., 1959. 889 p. Muganlinskiy F.F., Treger Yu.A., and Lyushin M.M. Khimiya i tekhnologiya galogenorganicheskikh soedineniy [Chemistry and technology of halogen organic compounds]. Moscow: Chemistry Publ., 1991. 71-78 pp. Muganlinskiy F.F., Treger Yu.A., and Lyushin M.M. Khimiya i tekhnologiya galogenorganicheskikh soedineniy [Chemistry and technology of halogen organic compounds]. Moscow: Chemistry Publ., 1991. 71-78 pp. Morrison R. and Boyt R. Organicheskaya khimiya [Organic chemistry]. Moscow: Mir Publ., 1974. 1133 p. Morrison R. and Boyt R. Organicheskaya khimiya [Organic chemistry]. Moscow: Mir Publ., 1974. 1133 p. Starostina T.I. and Zinov'eva T.I. Peritsiklicheskie reaktsii i orbital'naya simmetriya [Pericyclic reactions and orbital symmetry]. N. Novgorod: Nizhny Novgorod State University Publ., 2010. 53 p. Available at: http://www.unn.ru/books/met_files/starostina.pdf. (accessed 22 December 2017). Starostina T.I. and Zinov'eva T.I. Peritsiklicheskie reaktsii i orbital'naya simmetriya [Pericyclic reactions and orbital symmetry]. N. Novgorod: Nizhny Novgorod State University Publ., 2010. 53 p. Available at: http://www.unn.ru/books/met_files/starostina.pdf. (accessed 22 December 2017). Kaberdin R.V. and Potkin V.I. Trichlorethylene in organic-synthesis. Russian Chemical Reviews,1994, vol. 63, no. 8, pp. 673-692. (In Russian). Kaberdin R.V. and Potkin V.I. Trichlorethylene in organic-synthesis. Russian Chemical Reviews,1994, vol. 63, no. 8, pp. 673-692. (In Russian). Krasnova Т.А., Gorelkina А.К., and Kirsanov M.P. Use of adsorption to reduce the pollution of water resources. Ecology and industry of Russia, 2018, vol. 22, no. 1, pp. 44-49. DOI: 10.18412/1816-0395-2018-1-44-49. (In Russian). Krasnova T.A., Gorelkina A.K., and Kirsanov M.P. Use of adsorption to reduce the pollution of water resources. Ecology and industry of Russia, 2018, vol. 22, no. 1, pp. 44-49. DOI: 10.18412/1816-0395-2018-1-44-49. (In Russian).