Кемерово, Кемеровская область, Россия
Processing of raw materials, semi-finished and finished products with the help of a variety of aids is one of the most urgent methods of solving the problem of increasing beverage storage duration. The paper shows the state of a beverage as a disperse system during the process. In the semi-finished products at the beginning of technological chain the process of diffusion is not determined, thus the system of beverages experiences sedimentary instability. The processing of semi-finished and finished beverages before pre-packaging by various technological supplementary means leads to the formation of sedimentary stability, in which a sedimentation - diffusion equilibrium takes place. The hypothetical model of the state of beverage disperse system under the influence of technological supplementary means is demonstrated. Disperse system of beverages can be exposed in three main positions: sedimentary unstable, stable (equilibrium), excessively stable. The brief overview of characteristic features of supplementary means is presented, the latter being used in beverage technology to ensure the stability of products with the help of research data presented by domestic and foreign authors. One of the variants of classification of processing aids is the usage of hierarchical method. Structural and technological characteristics of the subsidiary materials used for durability of beverage upon storage are presented as a classification basis. Signs and stages of classification are marked. The presented embodiment of classification methodology can serve as a basis for the selection of processing with the help of supplementary methods, based on individual characteristics of the structural properties of complex means and substances involved in turbidity formation, as well as for indication of the parameters of materials rational usage in the production line as one of the fundamental factors for the formation of finished products quality.
Drinks, durability, technological supplementary means, antioxidants, enzymes, sorbents, flocculants, hierarchical classification method.
INTRODUCTION
A beverage, prepared from natural raw materials presents a complex multi-component, poly disperse system, being in certain equilibrium. A large proportion of beverage substances is arranged, due to their special characteristics (eg., taste, transparency) and is in a colloidal state. Being stored under the influence of various factors, an effect of violation of the physico-chemical equilibrium in the colloidal system of the beverage occurs, and turbidity is formed.
According to the terminology of technical regula-tions in accordance with the Customs Union “Safety of food additives, flavorings and processing supplementa-ry technological means”, substances or materials and their derivatives, which are not the components of food, intentionally are used in the processing of food raw material and in the production of food products for specific technological purposes, and they are removed after achieving the task from those materials, Such food products or residual amounts of them do not have the technological effect on the finished food product.
Processing methods, including the use of subsidiary materials designed to remove excess potential turbidity forming components, can intensify the clarification process and increase the terms of transparency in canned beverages. Processing of raw materials, semi-finished and finished products by a variety of aids is one of the important ways to solve the problem of in-creasing the resistance of beverages.
Supplementary means used in beverage technology to preserve the equilibrium of the colloidal system of drinks are quite diverse and differ in many ways.
The purpose of this research is to develop a classi-fication of technological supplementary means (TSM), taking into account their structural features and tech-nological orientation, as a methodological basis for the selection of (TSM), improvement of their processes and obtaining high-quality drinks.
OBJECTS AND METHODS OF STUDY
Objects of research are the scientific data of domestic and foreign sources of information. As for research methods, theoretical methods were used: a hypothetical method; methods of analysis and selection of information sources; generalization and systematization of information data; a hierarchical classification method [1].
1. Nikolaeva, M.A., Teoreticheskie osnovy tovarovedenija (Theoretical Foundations of merchandising), Moscow: Norma, 2007. 448p.
2. Gomez-Plaza, E., and Cano-Lopez, M., A review on micro-oxygenation of red wines: claims, benefits and the under-lying chemistry, Food Chemistry, 2011, no. 3, pp. 1131-1140.
3. Valuiki, G.G., Tehnologija vinogradnyh vin (Technology of wines), Simferopol: Tauris, 2001. 624 p.
4. Meledina, T.V., Syr´e i vspomogatel´nye materialy v pivovarenii (Raw and subsidiary materials in brewing), St. Pe-tersburg: “Professija” Publ., 2003. 304 p.
5. Sarafanova, L.A., Primenenie pishhevyh dobavok v industrii napitkov (The use of dietary supplements in the beve-rage industry), St. Petersburg: “Professija” Publ., 2007. 240 p.
6. Sidani, B., and Makris, D.P., Interactions of natural antioxidants with red grape pomace anthocyanins in a liquid model matrix: stability and copigmentation effects, Chemical industry and Chem. Eng. Quart., 2011, no. 1, pp. 59-66.
7. Kowalczyk, J., Hausmanns, S., and Dorr, T. Antioxidationsmittel auf Basis von Application Trehalulose. Patent Germ., no. 102008027686.3, 2009.
8. Ayala-Zavala, J.F., Rosas-Domingues, C., Vega-Vega, V., Palafox-Carlos, H., Villa-Rodrigues, J.A., Siddiqui, Md.Wasim., Davila, J.E., Gonzalez-Aguilar, G.A., Agro-industrial potential of exotic fruit byproducts as a source of food additives, Food Res. Int., 2011, no. 7, pp. 1866-1874.
9. Ajila, C.M., Brar, S.K., Verma, M., Tyagi, R.D., and Valero, J.R., Solid-state fermentation of apple pomace using Phanerocheate chrysosporium, liberation and extraction of phenolic antioxidants, Food Chemistry, 2011, no. 3, pp. 1071-1080.
10. Zhigang, T., Cai, L., Dai, L., Dong, L., Wang, M., Yang ,Y., Cao, Q, and Ding, Z., Antioxidant activity and chemical constituents of edible flower of Sophora viciifolia, Food Chemistry, 2011, no. 4, pp. 1648-1654.
11. Huo, L., Huo, R., Lu, P., LLi, Y. Liao, Chen, P., Deng, Ch., and Lu, X., Antioxidant activity, total phenolic, and total flavonoid of extracts from the stems of Jasminum nervosum Lour, Grasas y aceites, 2011, no. 2, pp. 149-154.
12. Liu, J., Wang, C., Wang, Z., Zhang, Ch., Lu, Sh., and Liu, J., The antioxidant and free-radical scavenging activities of extract and fractions from corn silk (Zea mays L.) and related flavones glycosides, Food Chemistry, 2011, no. 1, pp. 261-269.
13. Yu-Chi, Chen. Yu Shu-Huei, Tsai Guo-Jane, Tang Deh-Wei, MiFwu-Long, Peng, Yu-Ping., Novel technology for the preparation of self-assembled catechin, gelatin, nanoparticles and their characteristics, J. Arg. and Food Chem., 2010, no. 11, pp. 6728-6734.
14. Titze, J., Herrmann, A., and Ilberg, V., Ein chemisch-physikalischer erklarungsansatz, Brauindastries, 2012, no. 4, pp. 14-17.
15. Narciss, L., and Bak, V., Kratkij kurs pivovarenija (A Short Course of brewing), St. Petersburg: “Professija” Publ., 2007. 640 p.
16. Bible, C., Enzymes in the brewing process, Zymurgy, 2012, no. 4, pp. 53-56.
17. Stankovic, S., Jovic, S., Zivkovic, J., and Pavlovic, R., Influence of age on red wine color during fining with bento-nite and gelatin, Int. J. Food Prop., 2012, no. 2, pp. 326-335.
18. Ageev, N.M., Andreev, V.G., and Dunets, R.V., Obosnovanie rezhimov aktivacii montmorillonita dioksidom sery (Justification activation modes sulfur dioxide), Vinodelie i vinogradarstvo (Winemaking and Viticulture), 2012, no. 4, pp. 16-18.
19. Ageev, N.M., Gnetko, L.V., and Belyavtseva, T.A., Vlijanie fermentnyh preparatov na biopolimernyj kompleks plodovyh sokov (Influence of enzyme preparations on biopolymer complex of fruit juices), Vinodelie i vinogra-darstvo (Winemaking and Viticulture), 2012, no. 4, pp. 24-25.
20. Koshelev, Y.A., Kuleshov, N.I., Batashov, E.S., Sevodin, V.P., Chumichev, A.I., and Pyrozhkov, A.S., Sposob os-vetlenija oblepihovogo soka (Method of sea-buckthorn juice lightening). Patent RF, no. 2402960, 2006.
21. Sobolev, E.M., Stafionov, I.K., Mishin, M., and Talanyan, O.R., Sposob otrabotki susel i vinomaterialov betonitom (A method of processing musts and wine bentonite). Patent RF, no. 2224016, 2004.
22. Oganesyants, L.A., Reytblat, B.B., Dubinchuk, L.V., and Kucherjavyj, L. M., Sposob proizvodstva vina igristogo jablochnogo (A method of producing sparkling apple wine). Patent RF, no. 1124129, 2011.
23. Nikitin, P.V., and Novikov, I.L., Sposob proizvodstva neosvetlennogo i osvetlennogo koncentrata soka topinambura (A method of producing a clarified and unclarified concentrated juice of Jerusalem artichoke). Patent RF, no. 2444914, 2012.
24. Ulrich, S., Always bright: new regenerative beer stabilization system, Brewing and Beverage Industry, 2011, no. 5, pp. 64-66.
25. Bernhard, Gris, Sposob poluchenija prozrachnogo i rastvorimogo zernovogo jekstrata (A method for producing a transparent and soluble corn extract). Patent RF, DK, no. 2011137543/13, 2013.
26. Earl Graham James, Ian Patrick McKeown, Stabilizacija napitkov (Stabilization drinks) Patent WO, no. 02/057403, 2006.
27. Namazbayev, V.I., Tcharykov, N.A., Keskin, V.A., and Neumark, M.S., Sposob stabilizacii vinogradnogo vina (The method of stabilization of wine). Patent RF, no. 2418854, 2011.
28. Kreb, J., Kreb, M., Boehm, M., Duck, S., and Fratianni, A., kieselgurfreie anschwemm-filtration in bestehenden filterlinien, Brauindustrie, 2011, no. 4, pp. 38-42.
29. Kattske, Michael, Berglef, Yang, Vretblyud, Per, and Nendtsa, Ralph, Sposob stabilizacii napitkov (A method for stabilizing drinks). Patent WO, no. 97/43401, 2003.
30. Nimsh, K., and Nikolashkin, F.V., Silikazol´ i silikagel´ - aspektyk achestva (Silica sol and silica gel - aspects of quality), Pivo i napitki (Beer and beverages), 2005, no. 2, pp. 26-28.
31. Falk Uwe, Zhakono Eric, Peyrard Marie Laure, Primenenie kolloidnogo anionnogo kremnievogo zolja v kachestve osvetlitelja (The use of colloidal anionic silicasol as a clarifier). Patent WO, no. 2004/003128, 2008.
32. Beer stabilization: a profile of one of the pioneers of silica gel stabilization, Stabifix Braveries Technic: Brew. Guardian, 1998, no. 5, pp. 24-26.
33. Kilcast, D., and Subramaniam, P., Food and Beverage Stability and Shelf Life, Woodhead Publishing Series in Food Science, Technology and Nutrition, 2011, 849 p. (Russ. ed.: Kilcast, D., and Subramaniam, P., Stabil´nost´ i srok godnosti. Bezalkogol´nye napitki, soki, pivoi vino, St. Petersburg: “Professija” Publ., 2013. 384 p.).
34. Shatirishvili, Sh.I., Maharoblilze, M., and Tsereteli, Kh.Sh. Influence of different technological methods and mate-rials for fining wine colloidal stability, Bulletin of Agricultural Science, 2011, no. 3, pp. 94-96.
35. Avanesyants, R.V., Ageev, N.M., Avanesyants, R.A., and Jakub, Y.F., Sposob proizvodstva krepkogo napitka (Process of producing a strong drink). Patent RF, no. 2458115, 2012.
36. Burachevsky, I.I., Zaynullin, R.A., Kunakova, R.V., Polyakov, V.A., and Fedorenko, B.I., Proizvodstvo vodok i likerovodochnyh izdelij (Production of vodka and liqueurs), Moscow: DeLee print, 2009. 324 p.
37. Shcherbakov, S.S., Giryavenko, A.V., and Kolesnikova, V.F., Sposob obrabotki vinomaterialov (A method of processing and wine tasting). Patent RF, no. 2349639, 2009.
38. Polyakov, A.G., Shevchenko, N.N., Chernykh, V.S., and Smol´ianinov, V.V., Sposob osvetlenija soka (Method of clarifying juice). Patent RF, no. 2252261, 2005.
39. Sergeeva, I.Yu., Pomozova, V.A., Shevchenko, T.V., Syrovatko, A.L., and Zakharenko, D.G., Primenenie floku-lyantov dlya povysheniya stoykosti sbrozhennykh napitkov (Use of flocculants for increase of stability of fermented beverages), Pivo i napitki (Beer and beverages), 2007, no. 5,pp. 24-27.
40. Pomozova, V.A., Sergeeva, I.Yu., Kiseleva, T.F., Shevchenko, T.V., and Bikmulina, N.O., Ispol´zovanie flokulyan-tov dlya udaleniya polifenolov iz spirtovannykh morsov (Use of flocculants with the aim of removing polyphenols from alcohol based beny juices), Proizvodstvo spirta i likerovodochnyh izdelij (Manufacture of alcohol liqueur & vodka products), 2005, no. 1, pp. 17-19.
41. Sergeeva, I.Yu, Shafray, A.V., and Zakharenko, D.G., Modelirovanie protsessa osvetleniya napitkov brozheniya s pomoshch´yu vspomogatel´nykh sredstv (Modeling of clarification process of fermentation drinks with subsidiary substances), Technika i technologiia pishchevykh proizvodstv (Food Processing: Techniques and Technology), 2013, no. 3 (30), pp. 58-61.
42. Phillips, G.O., and Williams, P.A., Spravochnik po ghidrokolloidam (Handbook of hydrocolloids), St. Petersburg: GIORD, 2006. 536 p.
43. Prokhorova, A.V., Novye tendentsii na rynke gidrokolloidov (New trends in the market hydrocolloids), Prodindu-striya, 2005, no. 3, pp. 90-92.
44. Yang Ling-Yu, Zhang Jian-Lei, Basset Carole L., and Meng Xian-Hong, Difference between chitosan and oligochi-tosan in growth of Monilinia fructicola and control of brown rot in peach fruit, LWT “Food Science and Technolo-gy", 2012, no. 1, pp. 254-259.
45. Alvares, Maria V., Ponce Alejandra G., Moreira Maria del R., Antimicrobial efficiency of chitosan coating enriched with bioactive compounds to improve the safety of fresh cut broccoli, LWT - Food Science and Technology, 2013, no. 1, pp. 78-87.
46. Safronova, T.M., Maksimova, S.N., Bobyleva, A.E., Shafray, A.V., Sposob osvetleniya plodovo-yagodnogo soka (Way of fruit juice clarification). Patent RF, no. 98117099/13, 2000.
47. Sergeeva, I.Yu., Pomozova, V.A., Vechtomova, E.A., and Kuzmin, K.V., Primenenie prirodnyh stabilizatorov v tehnologii likerovodochnyh izdelij (The use of natural stabilizers in technology of liquors), Proizvodstvo spirta i li-kerovodochnyh izdelij (Manufacture of alcohol liqueur & vodka products), 2011, no. 3, pp. 28-30.
48. Sergeeva, I.Yu., Pomozova, V.A., Vechtomova, E.A., and Kuzmin, K.V., Ocenka vlijanija hitozana na udalenie biopolimernyh komponentov pomutnenij napitkov (Assessing the impact of the removal of the biopolymer chitosan components opacities of drinks), Pivo i napitki (Beer and beverages), 2013, no. 3, pp. 28-30.